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Solid Oxide Fuel Cells

Discussions of conventional and alternative energy production technologies.

Solid Oxide Fuel Cells

Unread postby Rune » Mon 28 Oct 2013, 15:02:58

A Major Advance In Fuel Cells

A one-meter-square gray box studded 
with green lights sits in a hallway near the laboratory of materials scientist Eric ­Wachsman, director of the Energy Research Center at the University of Maryland. It is a mockup of a fuel-cell device that runs on natural gas, producing electricity at the same cost as a large gas plant.

The box is designed to house stacks of solid-oxide fuel cells that differ from their conventional counterparts in a dramatic way: they’re projected to produce electricity for $1 per watt, down from $8 in today’s commercial versions, thanks to improvements that ­Wachsman has made in the ceramic materials at their heart.

The technology could eventually become a practical and affordable way to ease strain on the increasingly stressed electricity grid; anywhere there’s cheap natural gas, we could also have constant and cheap electricity.

That would make it possible to do away with the diesel generators that are now widely used for backup power and as a key component of microgrids in places like Malaysia and cellular base stations in rural areas around the world. Solid-oxide fuel cells—which can run on diesel fuel or gasoline, not just natural gas—use much less fuel per watt than diesel generators of similar size.

Conventional solid-oxide fuel cells run at high temperatures, making them more expensive and prone to performance losses. A key advance in the Maryland fuel cell is that it is based on cerium oxide and bismuth oxide, which are far more electrically conductive than materials used in commercial versions and produce much more electricity per square centimeter. The cell can operate at 650 °C, down from 900 °C in existing products, reducing thermal stresses and insulation needs. And the final product is made of 32 stacks, each of which can be replaced if it fails.

The gray box mocks up a 25-kilowatt version of the technology, which is now under development by a startup called Redox Power Systems. Redox is building a factory in Melbourne, Florida, and hopes to launch the product in 2014. A 25-kilowatt fuel cell is enough to power a small strip mall; units that are smaller still could serve a single house. In the long term, the technology could even be put into hybrid vehicles to charge their batteries, since it is both lighter than an internal-­combustion engine and more efficient at producing electricity.

But the stand-alone generators, if successful, would be impressive enough. They’d mean “we’re on par with conventional power generation,” Wachsman says. “It’s not just backup power—it’s energy security.”


Redox SOFC Gives Li-Ion Batteries A run For Their Money

While lithium-ion batteries are current champs of the electric vehicle market, fuel cells are beginning to come on strong. If that trend continues it raises some intriguing future scenarios, namely, fuel cells could eventually squeeze out Li-ion batteries altogether, or both technologies could co-exist to some degree, engaging in a continuous battle for market share. There is also a third possibility, which is that the EV of the future will be an ultra long-range, super quick-charging model using a fuel cell in combination with a battery, and that’s where a new fuel cell from the company Redox Power could come in.


Solid Oxide Fuel Cells double efficiency over internal combustion engines. Products are due out in 2014.

We might as well have a thread to follow this technology because its a major advance in conservation.
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Re: Solid Oxide Fuel Cells

Unread postby Peak Spud » Wed 30 Oct 2013, 12:58:54

Thanks for the thread - solid oxide fuel cells are of great interest to me, as I used to be a Ceramic Engineer a long time ago in a land far away. The reduction in operating temperature of these new fuel cells is very encouraging. 650 C is about 1200 F, so it's still very hot and would be tricky to use in an automobile.

I'm also wondering if the fuel cell could be run in reverse, where electricity generated by solar cells could take the products expelled by processing the natural gas and reform it. Probably not thermodynamically profitable, but it's interesting to consider.

Again, I'd have to do the research, but I'm guessing the bismuth oxide would be readily available but the cerium oxide is more difficult to come by. That's part of the reason Li-ion batteries have not taken off, due to limits in lithium availability. Lead-acid batteries - no problem.
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Re: Solid Oxide Fuel Cells

Unread postby kuidaskassikaeb » Thu 31 Oct 2013, 14:44:49

These are kind of cool in another way for the doomers here. They can be very small, and if they can improve the catalysts you could burn wood in them, for electricity. These could be used for single family generators. They use the same basic technology as the oxygen sensor in your car, so its not that hard.
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Re: Solid Oxide Fuel Cells

Unread postby Shaved Monkey » Fri 01 Nov 2013, 00:24:08

Bluegen was an Australian invention now European owned.
Natural gas to electricity and hot water
http://www.enviroshop.com.au/info/cogeneration
http://www.cfcl.com.au/
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